if you're on steam, go to the gear icon on the right, properties -> installed files -> browse... -> MarvelRivals\MarvelGame\Marvel\Content\Paks\~mods Epic Games is probably (i play on steam) the same method, just go to the files and then follow that path
if you don't have a "~mods" folder, you can simply create a new folder in Paks and name it ~mods then you unzip the download in ~mods, and you should have the skin in the game.
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-> MarvelRivals\MarvelGame\Marvel\Content\Paks\~mods
Epic Games is probably (i play on steam) the same method, just go to the files and then follow that path
if you don't have a "~mods" folder, you can simply create a new folder in Paks and name it ~mods
then you unzip the download in ~mods, and you should have the skin in the game.